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A study on the optical properties and optoelectronic parameters of Sudan dye doped poly(5-hydroxy-L-tryptophane) and P(TER-CO-TRI) polymers

Barham K. Rahim 1
Barham K. Rahim
,  , 
Salah R. Saeed 3
Salah R. Saeed
, 
Kamal A. Ketuly 4
Kamal A. Ketuly
1 Medical Physics Department, Faculty of Medicals & Applied Science, Charmo University, Chamchamal 46023, Kurdistan Region, Sulaimania, Iraq
2 Department of Physics, Faculty of Science and Health, Koya University, Koya 44023, Kurdistan Region-F.R., Iraq
3 Advanced Polymeric Materials Research Lab., Department of Physics, College of Science, University of Sulaimani, Qlyasan Str., Sulaimani 46001, Iraq
4 Department of Medical Chemistry, College of Medicine, University of Duhok, 38 Zakho Str., Duhok 1006, Kurdistan Region, Iraq
10.3897/j.moem.8.3.91521
Published 14 October 2022
Communication , Volume 8, Issue 3, 85-96
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Rahim B. K. et al. A study on the optical properties and optoelectronic parameters of Sudan dye doped poly(5-hydroxy-L-tryptophane) and P(TER-CO-TRI) polymers // Modern Electronic Materials. 2022. Vol. 8. No. 3. pp. 85-96.
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Rahim B. K., Muhammadsharif F. F., Saeed S. R., Ketuly K. A. A study on the optical properties and optoelectronic parameters of Sudan dye doped poly(5-hydroxy-L-tryptophane) and P(TER-CO-TRI) polymers // Modern Electronic Materials. 2022. Vol. 8. No. 3. pp. 85-96.
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TY - JOUR
DO - 10.3897/j.moem.8.3.91521
UR - https://moem.colab.ws/publications/10.3897/j.moem.8.3.91521
TI - A study on the optical properties and optoelectronic parameters of Sudan dye doped poly(5-hydroxy-L-tryptophane) and P(TER-CO-TRI) polymers
T2 - Modern Electronic Materials
AU - Rahim, Barham K.
AU - Muhammadsharif, Fahmi F.
AU - Saeed, Salah R.
AU - Ketuly, Kamal A.
PY - 2022
DA - 2022/10/14
PB - НИТУ МИСИС
SP - 85-96
IS - 3
VL - 8
ER -
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@article{2022_Rahim,
author = {Barham K. Rahim and Fahmi F. Muhammadsharif and Salah R. Saeed and Kamal A. Ketuly},
title = {A study on the optical properties and optoelectronic parameters of Sudan dye doped poly(5-hydroxy-L-tryptophane) and P(TER-CO-TRI) polymers},
journal = {Modern Electronic Materials},
year = {2022},
volume = {8},
publisher = {НИТУ МИСИС},
month = {Oct},
url = {https://moem.colab.ws/publications/10.3897/j.moem.8.3.91521},
number = {3},
pages = {85--96},
doi = {10.3897/j.moem.8.3.91521}
}
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Rahim, Barham K., et al. “A study on the optical properties and optoelectronic parameters of Sudan dye doped poly(5-hydroxy-L-tryptophane) and P(TER-CO-TRI) polymers.” Modern Electronic Materials, vol. 8, no. 3, Oct. 2022, pp. 85-96. https://moem.colab.ws/publications/10.3897/j.moem.8.3.91521.
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Keywords

dielectric constant
energy band gap
extinction coefficient
optical conductivity
P(TER-CO-TRI)
poly(5-hydroxy-L-Tryptophane)
refractive index
sudan dye

Abstract

In this paper, the optical properties and optoelectronic parameters of two newly synthesized polymers forming a donor : acceptor (D : A) binary system are investigated, followed by their subsequent doping with Sudan dye to obtain a ternary system. The donor polymer is P(TER-CO-TRI), while the acceptor is poly(5-hydroxy-L-Tryptophane). A cost-effective solution-processing was carried out to obtain different binary and ternary composites with concentration of 0.5 mg/ml. Optical absorption spectroscopy was used to measure the optical response and optoelectronic parameters, while FTIR and cyclic voltammetry were used to assess the structure and molecular energy levels of the polymers. The results revealed that the non-dispersive refractive index and energy gap of binary D : A was decreased from 1.56 to 1.52 eV and from 2.84 to 2.10 eV, respectively, when it was doped with Sudan dye. It was concluded that with the help of doping process, different values of energy band gap, refractive index, dielectric constant, and optical conductivity are achieved. This tuning achievement of the optoelectronic parameters is crucial in determining the possible applications of these materials in the organic electronics, photodiodes and photovoltaic devices.

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