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Degradation of the electrical conductivity of charged domain walls in reduced lithium niobate crystals

, 
Tatiana S. Ilina 1
Tatiana S. Ilina
,  ,  , 
Aleksandr A. Temirov 1
Aleksandr A. Temirov
,  ,  , 
Mikhail D. Malinkovich 1
Mikhail D. Malinkovich
, 
1 National University of Science and Technology MISiS, 4-1 Leninsky Ave., Moscow 119049, Russia
2 Federal State Research and Develpment Institute of Rare Metal Industry (Giredmet JSC), 2 Elektrodnaya Str., Moscow 111524, Russia
Published 12 April 2022
Communication , Volume 8, Issue 1, 15-22
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Kislyuk A. M. et al. Degradation of the electrical conductivity of charged domain walls in reduced lithium niobate crystals // Modern Electronic Materials. 2022. Vol. 8. No. 1. pp. 15-22.
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Kislyuk A. M., Ilina T. S., Kubasov I. V., Kiselev D. A., Temirov A. A., Turutin A. V., Shportenko A. S., Malinkovich M. D., Parkhomenko Y. N. Degradation of the electrical conductivity of charged domain walls in reduced lithium niobate crystals // Modern Electronic Materials. 2022. Vol. 8. No. 1. pp. 15-22.
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TY - JOUR
DO - 10.3897/j.moem.8.1.85251
UR - https://moem.colab.ws/publications/10.3897/j.moem.8.1.85251
TI - Degradation of the electrical conductivity of charged domain walls in reduced lithium niobate crystals
T2 - Modern Electronic Materials
AU - Kislyuk, Aleksandr M.
AU - Ilina, Tatiana S.
AU - Kubasov, Ilya V.
AU - Kiselev, Dmitry A.
AU - Temirov, Aleksandr A.
AU - Turutin, Andrei V.
AU - Shportenko, Andrey S.
AU - Malinkovich, Mikhail D.
AU - Parkhomenko, Yuri N.
PY - 2022
DA - 2022/04/12
PB - НИТУ МИСИС
SP - 15-22
IS - 1
VL - 8
ER -
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@article{2022_Kislyuk,
author = {Aleksandr M. Kislyuk and Tatiana S. Ilina and Ilya V. Kubasov and Dmitry A. Kiselev and Aleksandr A. Temirov and Andrei V. Turutin and Andrey S. Shportenko and Mikhail D. Malinkovich and Yuri N. Parkhomenko},
title = {Degradation of the electrical conductivity of charged domain walls in reduced lithium niobate crystals},
journal = {Modern Electronic Materials},
year = {2022},
volume = {8},
publisher = {НИТУ МИСИС},
month = {Apr},
url = {https://moem.colab.ws/publications/10.3897/j.moem.8.1.85251},
number = {1},
pages = {15--22},
doi = {10.3897/j.moem.8.1.85251}
}
MLA
Cite this
MLA
Kislyuk, Aleksandr M., et al. “Degradation of the electrical conductivity of charged domain walls in reduced lithium niobate crystals.” Modern Electronic Materials, vol. 8, no. 1, Apr. 2022, pp. 15-22. https://moem.colab.ws/publications/10.3897/j.moem.8.1.85251.
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Keywords

bidomain crystal
charged domain wall
diffusion annealing
lithium niobate
piezoresponse force microscopy
reduction annealing

Abstract

In this work, the effect of long-term room temperature exposure on the electrical conductivity of the charged domain wall (CDWs) in nonpolar x-cut congruent lithium niobate (LiNbO3, LN) crystals has been studied. Bidomain ferroelectric structures containing head-to-head charged domain boundaries have been produced by diffusion annealing in air near the Curie temperature and by infrared annealing. The crystals have been reduction annealed in a nitrogen atmosphere for the formation of color centers and growth of the electrical conductivity. The current measured during the recording of the I-V curves of the specimens using scanning probe microscope after room temperature exposure for 91 days has been found to decrease. The effect of storage conditions on the electrical conductivity of the CDWs has been studied. Degradation of the electrical conductivity does not originate from the effect of environment on the crystal surface. It has been hypothesized that the degradation is caused by distribution of charge carriers shielding the bound charge of the CDWs.

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