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Magnetoelectric properties of PVDF-CoFe 2O 4 composite films obtained by 3D printing

,  ,  ,  ,  , 
Ismel Musov
Ismel Musov
, 
Khasan Musov
Khasan Musov
, 
Svetlana Khashirova
Svetlana Khashirova
,  ,  ,  , 
10.3897/j.moem.11.3.143766
Published 1 October 2025
Communication , Volume 11, Issue 3, 139-146
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Ershov P. et al. Magnetoelectric properties of PVDF-CoFe 2O 4 composite films obtained by 3D printing // Modern Electronic Materials. 2025. Vol. 11. No. 3. pp. 139-146.
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Ershov P., Omelyanchik A., Vorontsov P., Amirov A., Zhansitov A., Musov I., Musov K., Khashirova S., Savin V., Ignatov A., Panina L., Rodionova V. Magnetoelectric properties of PVDF-CoFe 2O 4 composite films obtained by 3D printing // Modern Electronic Materials. 2025. Vol. 11. No. 3. pp. 139-146.
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TY - JOUR
DO - 10.3897/j.moem.11.3.143766
UR - https://moem.colab.ws/publications/10.3897/j.moem.11.3.143766
TI - Magnetoelectric properties of PVDF-CoFe 2O 4 composite films obtained by 3D printing
T2 - Modern Electronic Materials
AU - Ershov, Petr
AU - Omelyanchik, Alexander
AU - Vorontsov, Pavel
AU - Amirov, Abdulkarim
AU - Zhansitov, Azamat
AU - Musov, Ismel
AU - Musov, Khasan
AU - Khashirova, Svetlana
AU - Savin, Valerii
AU - Ignatov, Artem
AU - Panina, Larissa
AU - Rodionova, Valeria
PY - 2025
DA - 2025/10/01
PB - НИТУ МИСИС
SP - 139-146
IS - 3
VL - 11
ER -
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@article{2025_Ershov,
author = {Petr Ershov and Alexander Omelyanchik and Pavel Vorontsov and Abdulkarim Amirov and Azamat Zhansitov and Ismel Musov and Khasan Musov and Svetlana Khashirova and Valerii Savin and Artem Ignatov and Larissa Panina and Valeria Rodionova},
title = {Magnetoelectric properties of PVDF-CoFe 2O 4 composite films obtained by 3D printing},
journal = {Modern Electronic Materials},
year = {2025},
volume = {11},
publisher = {НИТУ МИСИС},
month = {Oct},
url = {https://moem.colab.ws/publications/10.3897/j.moem.11.3.143766},
number = {3},
pages = {139--146},
doi = {10.3897/j.moem.11.3.143766}
}
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Ershov, Petr, et al. “Magnetoelectric properties of PVDF-CoFe 2O 4 composite films obtained by 3D printing.” Modern Electronic Materials, vol. 11, no. 3, Oct. 2025, pp. 139-146. https://moem.colab.ws/publications/10.3897/j.moem.11.3.143766.
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Keywords

3D printing
fluoropolymer
magnetic nanoparticles
magnetoelectric composites
polymer composites
PVDF

Abstract

In this paper, we have investigated piezoelectric, magnetic and magnetoelectric properties of composite materials, consisting of polyvinylidene fluoride (PVDF) matrix and CoFe2O4 nanoparticles in the form of filament extrusion and 3D printed films. We used PVDF powders from different manufacturers each with different molecular weights and phase compositions. For PVDF with lower molecular weight and higher electroactive phase content of the, we observed that approximately 80 % of the electroactive phase in the starting polymer was effectively transferred to the printed films through all technological stages. The composite filaments exhibited ferromagnetic behavior with a large coercive force of 1.7±0.1 kOe consistent with a particle size of about 20 nm. The magnetoelectric coefficient was about 2 mV/(Oe∙cm) for printed composite films from both precursors, which is sufficient for a range of applications including microelectronics and tissue engineering using magnetically stimulated electric fields.

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