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Thermovoltaic response in two-layered thin-film zinc oxide structures

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10.3897/j.moem.10.3.140732
Published 10 October 2024
Communication , Volume 10, Issue 3, 159-165
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Makagonov V. A. et al. Thermovoltaic response in two-layered thin-film zinc oxide structures // Modern Electronic Materials. 2024. Vol. 10. No. 3. pp. 159-165.
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Makagonov V. A., Gabriel’s K. S., Kalinin Y. E., Lopatin A. Y., Bliznyuk L. A., Fedotov A. K. Thermovoltaic response in two-layered thin-film zinc oxide structures // Modern Electronic Materials. 2024. Vol. 10. No. 3. pp. 159-165.
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TY - JOUR
DO - 10.3897/j.moem.10.3.140732
UR - https://moem.colab.ws/publications/10.3897/j.moem.10.3.140732
TI - Thermovoltaic response in two-layered thin-film zinc oxide structures
T2 - Modern Electronic Materials
AU - Makagonov, Vladimir A.
AU - Gabriel’s, Konstantin S.
AU - Kalinin, Yuri E.
AU - Lopatin, Artem Yu.
AU - Bliznyuk, Ludmila A.
AU - Fedotov, Alexander K.
PY - 2024
DA - 2024/10/10
PB - НИТУ МИСИС
SP - 159-165
IS - 3
VL - 10
ER -
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@article{2024_Makagonov,
author = {Vladimir A. Makagonov and Konstantin S. Gabriel’s and Yuri E. Kalinin and Artem Yu. Lopatin and Ludmila A. Bliznyuk and Alexander K. Fedotov},
title = {Thermovoltaic response in two-layered thin-film zinc oxide structures},
journal = {Modern Electronic Materials},
year = {2024},
volume = {10},
publisher = {НИТУ МИСИС},
month = {Oct},
url = {https://moem.colab.ws/publications/10.3897/j.moem.10.3.140732},
number = {3},
pages = {159--165},
doi = {10.3897/j.moem.10.3.140732}
}
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Makagonov, Vladimir A., et al. “Thermovoltaic response in two-layered thin-film zinc oxide structures.” Modern Electronic Materials, vol. 10, no. 3, Oct. 2024, pp. 159-165. https://moem.colab.ws/publications/10.3897/j.moem.10.3.140732.
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Keywords

doping impurity
thermovoltaic effect
zinc oxide

Abstract

A method of measuring the thermovoltaic effect in heterogeneous media with gradient doping impurity distributions producing gradient carrier distributions has been proposed. Iron doped zinc oxide specimens have been produced using ion beam sputtering on thin foil tantalum substrates for thermovoltaic effect measurements, glass-ceramic substrates for Hall measurements and silicon substrates for structural study. The doping impurity concentration хFe in the specimens has been varied from 0.34 to 4.18 at.%. X-ray phase analysis has shown that all the specimens have a hexagonal zinc oxide crystal structure. The films have preferential [002] orientation. The carrier concentration in the experimental specimen layers according Hall data obtained on an ECOPIA 5500 measurement system in a 0.5 T DC magnetic field has varied in the 1016–1020 cm-3 range. The specimens have an n-type conductivity. Thermovoltaic measurements have been carried out for two-layered iron doped zinc oxide specimens with different carrier and iron doping impurity concentrations using the method proposed. The maximum thermovoltaic response (U ~ 80 μV) has been observed in the two-layered thin-film specimen with the carrier concentration difference between the layers (Δn ≈ 2∙103 cm-3). The observed saturation of the thermovoltaic response has been attributed to the establishment of dynamic equilibrium between carrier diffusion from the high carrier concentration layer to the low carrier concentration layer and carrier drift due to internal electric field.

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