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Comparison of the structure and physicochemical properties of ZrO2 based crystals partially stabilized with Y2O3, Gd2O3 and Sm2O3

Artem S. Chislov 1
Artem S. Chislov
,  ,  ,  ,  ,  , 
Aleksey A. Reu 1
Aleksey A. Reu
,  , 
Natalya V. Sidorova 2
Natalya V. Sidorova
, 
1 Prokhorov General Physics Institute of the Russian Academy of Sciences, 38 Vavilov Str., Moscow 119991, Russian Federation
2 Ogarev Mordovia State University, 68/1 Bolshevistskaya Str., Saransk, Republic of Mordovia 430005, Russian Federation
10.3897/j.moem.10.1.122043
Published 3 April 2024
Communication , Volume 10, Issue 1, 3-10
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Chislov A. S. et al. Comparison of the structure and physicochemical properties of ZrO2 based crystals partially stabilized with Y2O3, Gd2O3 and Sm2O3 // Modern Electronic Materials. 2024. Vol. 10. No. 1. pp. 3-10.
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Chislov A. S., Borik M. A., Kulebyakin A. V., Lomonova E. E., Milovich F. O., Myzina V. A., Reu A. A., Ryabochkina P. A., Sidorova N. V., Tabachkova N. Y. Comparison of the structure and physicochemical properties of ZrO2 based crystals partially stabilized with Y2O3, Gd2O3 and Sm2O3 // Modern Electronic Materials. 2024. Vol. 10. No. 1. pp. 3-10.
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TY - JOUR
DO - 10.3897/j.moem.10.1.122043
UR - https://moem.colab.ws/publications/10.3897/j.moem.10.1.122043
TI - Comparison of the structure and physicochemical properties of ZrO2 based crystals partially stabilized with Y2O3, Gd2O3 and Sm2O3
T2 - Modern Electronic Materials
AU - Chislov, Artem S.
AU - Borik, Mikhail A.
AU - Kulebyakin, Aleksey V.
AU - Lomonova, Elena E.
AU - Milovich, Filipp O.
AU - Myzina, Valentina A.
AU - Reu, Aleksey A.
AU - Ryabochkina, Polina A.
AU - Sidorova, Natalya V.
AU - Tabachkova, Nataliya Yu.
PY - 2024
DA - 2024/04/03
PB - НИТУ МИСИС
SP - 3-10
IS - 1
VL - 10
ER -
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@article{2024_Chislov,
author = {Artem S. Chislov and Mikhail A. Borik and Aleksey V. Kulebyakin and Elena E. Lomonova and Filipp O. Milovich and Valentina A. Myzina and Aleksey A. Reu and Polina A. Ryabochkina and Natalya V. Sidorova and Nataliya Yu. Tabachkova},
title = {Comparison of the structure and physicochemical properties of ZrO2 based crystals partially stabilized with Y2O3, Gd2O3 and Sm2O3},
journal = {Modern Electronic Materials},
year = {2024},
volume = {10},
publisher = {НИТУ МИСИС},
month = {Apr},
url = {https://moem.colab.ws/publications/10.3897/j.moem.10.1.122043},
number = {1},
pages = {3--10},
doi = {10.3897/j.moem.10.1.122043}
}
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Chislov, Artem S., et al. “Comparison of the structure and physicochemical properties of ZrO2 based crystals partially stabilized with Y2O3, Gd2O3 and Sm2O3.” Modern Electronic Materials, vol. 10, no. 1, Apr. 2024, pp. 3-10. https://moem.colab.ws/publications/10.3897/j.moem.10.1.122043.
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Keywords

directional crystallization
growth from melt
partially stabilized zirconia
toughness

Abstract

The phase composition, density, microhardness and fracture toughness of (ZrO2)1-x(R2O3)х crystals (where R = Y, Sm and Gd) for x = 0.02–0.04 have been compared. The crystals have been grown using directional melt crystallization in a cold crucible. The phase composition of the crystals has been studied using X-ray diffraction and Raman spectroscopy. The microhardness and fracture toughness of the crystals have been evaluated by means of indentation. At stabilizing oxide concentrations of ≥ 2.8 mol.% for Y2O3 and Gd2O3 and ≥ 3.7 mol.% for Sm2O3 the crystals have densities close to the theoretical ones and contain two tetragonal phases. At lower stabilizing oxide concentrations the crystals contain the monoclinic phase. The fracture toughness of the tetragonal crystals increases with the ionic radius of the stabilizer. The highest fracture toughness values achieved when stabilized by a specific oxide are 11.0, 13.0 and 14.3 MPa·m1/2 for the 2.8YSZ, 2.8GdSZ and 3.7SmSZ crystals, respectively. The fracture toughness proves to depend on the crystallographic orientation of the crystals. The results of this work can be used in the design and fabrication of various structural components and devices.

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